Noble Metal Nanoparticles Stabilized by Cyclodextrins: A Pertinent Partnership for Catalytic Applications

被引:15
|
作者
Denicourt-Nowicki, A. [1 ,2 ]
Roucoux, A. [1 ,2 ]
机构
[1] Ecole Natl Super Chim Rennes, CNRS, UMR 6226, F-35708 Rennes 7, France
[2] Univ Europeenne Bretagne, Rennes, France
关键词
Nanoparticles; Noble metal; Cyclodextrins; Catalysis; Water; CAPPED PALLADIUM NANOPARTICLES; GAS-PHASE HYDROGENATION; O-XYLENE HYDROGENATION; BETA-CYCLODEXTRIN; GOLD NANOPARTICLES; METHYLATED CYCLODEXTRINS; RUTHENIUM NANOPARTICLES; ARENE HYDROGENATION; SUPRAMOLECULAR SHUTTLE; ALPHA-CYCLODEXTRIN;
D O I
10.2174/138527210791616911
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
For economic and ecological purposes, the design of stable and reusable noble metal nanoparticles in water has become a concern over the past few years. Among the various water-soluble protective agents, cyclodextrins proved to be attractive candidates to efficiently stabilize catalytically active nanospecies in aqueous media and also to improve the mass transfer in aqueous-organic two-phase systems. Various catalytic reactions such as arenes hydrogenations, olefins reduction or cross-coupling reactions were successfully achieved with good yields and selectivities according to the relevant choice of the cyclodextrins (cavity or functionalization).
引用
收藏
页码:1266 / 1283
页数:18
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