Asymmetric autocatalysis triggered by triglycine sulfate with switchable chirality by altering the direction of the applied electric field

被引：7

作者：

Kawasaki, Tsuneomi ^{[1
]}

Kaimori, Yoshiyasu ^{[1
]}

Shimada, Seiya ^{[1
]}

Hara, Natsuki ^{[1
]}

Sato, Susumu ^{[1
]}

Suzuki, Kenta ^{[1
]}

Asahi, Toru ^{[2
]}

Matsumoto, Arimasa ^{[1
,4
]}

Soai, Kenso ^{[1
,3
]}

机构：

[1] Tokyo Univ Sci, Dept Appl Chem, Shinjuku Ku, Tokyo 1628601, Japan

[2] Waseda Univ TWIns, Dept Life Sci & Med Biosci, Shinjuku Ku, Wakamatsu Cho, Tokyo 1628480, Japan

[3] Waseda Univ, Res Org Nano & Life Innovat, Shinjuku Ku, Wasedatsurumaki Cho, Tokyo 1620041, Japan

[4] Nara Womens Univ, Dept Chem Biol & Environm Sci, Kita Uoya Nishi Machi, Nara 6308506, Japan

来源：

CHEMICAL COMMUNICATIONS | 2021年 / 57卷 / 49期

基金：

日本学术振兴会;

关键词：

CIRCULARLY-POLARIZED-LIGHT; SYMMETRY-BREAKING; ENANTIOSELECTIVE SYNTHESIS; GLYCINE SULFATE; AMPLIFICATION; MOLECULES; MECHANISM; PHASE; QUANTIFICATION; HOMOCHIRALITY;

D O I：

10.1039/d1cc02162a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Triglycine sulfate (TGS) acts as a chiral trigger for asymmetric autocatalysis with amplification of enantiomeric excess, i.e., the Soai reaction. Therefore, molecular chirality of highly enantioenriched organic compounds is controlled by a ferroelectric crystal TGS, whose polarization is altered by an electric field.

引用

页码：5999 / 6002

页数：4

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