An unexpected 3D (6,8)-connected metal-organic framework {[Cu5(trz)2(mal)2(fma)(H2O)4]•2H2O}n: Synthesis, structure and catalytic thermodecomposition for ammonium perchlorate

被引：18
|
作者：
Yang, Qi [1 ]
Chen, Sanping [1 ]
Gao, Shengli [1 ]
机构：
[1] NW Univ Xian, Key Lab Synthet & Nat Funct Mol Chem, Minist Educ, Coll Chem & Mat Sci, Xian 710069, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 12期
基金：
中国国家自然科学基金;
关键词：
Metal-organic framework; 1,2,4-Triazole; Fumarate; Malate; Catalytic thermodecomposition; HYDROTHERMAL SYNTHESIS; ENERGETIC COMPOUNDS; CRYSTAL-STRUCTURES; SALTS; POLYMERS; THERMOLYSIS; MONONUCLEAR; CHEMISTRY; CLUSTER; ZINC;
D O I：
10.1016/j.inoche.2009.09.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A crystalline 3D MOF ([Cu-5(trz)(2)(mal)(2)(fma)(H2O)(4)]center dot 2H(2)O)(n) (1) (trz = 1,2,4-triazolate, mal = malate, fma = fumarate) has been synthesized through hydrothermal method and characterized by X-ray crystallography, IR, elemental analysis and thermal gravimetric analysis. The crystal structure revealed that the fma was partly in situ converted into the mal under hydrothermal conditions and the compound was consisted of a 3D (6, 8)-connected honeycomb-like network. Furthermore, the catalytic performance of compound for the thermal decomposition of ammonium perchlorate (AP) was investigated by DSC. The experiment results indicated that the compound accelerated the decomposition of AP. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码：1224 / 1226
页数：3
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