A coumarin-based derivative (1), a highly selective and sensitive turn-on fluorogenic probe for the detection of HSO4- ions in aqueous solution, has been designed and synthesized. Various spectroscopic and DFT calculations revealed that H-bonding between the phenolic -OH and imine nitrogen of 1 played a crucial role in its high selectivity for HSO4-.
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Korea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
KIST Sch UST, Dept Biol Chem, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Hong, Seong Cheol
Murale, Dhiraj P.
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Korea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
KIST Sch UST, Dept Biol Chem, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Murale, Dhiraj P.
Lee, Minju
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GeorgiaTech, Sch Chem & Biomol Engn, 311 Ferst Dr NW, Atlanta, GA USAKorea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Lee, Minju
Lee, Seung Mi
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Seoul Natl Univ, Coll Med, Dept Obstet & Gynecol, Seoul, South KoreaKorea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Lee, Seung Mi
Park, Joong Shin
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Seoul Natl Univ, Coll Med, Dept Obstet & Gynecol, Seoul, South KoreaKorea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
Park, Joong Shin
Lee, Jun-Seok
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Korea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea
KIST Sch UST, Dept Biol Chem, 5 Hwarang Ro 14 Gil, Seoul 02792, South KoreaKorea Inst Sci & Technol, Mol Recognit Res Ctr, 5 Hwarang Ro 14 Gil, Seoul 02792, South Korea