Synthesis of redox-active biscalix[4]quinones and their electrochemical properties

被引：18
|
作者：
Tantrakarn, K [1 ]
Ratanatawanate, C [1 ]
Pinsuk, T [1 ]
Chailapakul, O [1 ]
Tuntulani, T [1 ]
机构：
[1] Chulalongkorn Univ, Fac Sci, Dept Chem, Bangkok 10330, Thailand
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 01期
关键词：
biscalixarene; quinone; cyclic voltammetry;
D O I：
10.1016/S0040-4039(02)02520-0
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Biscalix[4]arenes, 7 and 8, have been synthesized by a one-pot coupling method and a stepwise approach, respectively. A one-pot reaction in a pressurized vessel resulted in the symmetric biscalix[4]arene 7 in high yield. Oxidation of compounds 7 and 8 by Tl(CO2CF3)(3) in CF3COOH yielded biscalix[4]quinones, 9 and 10, respectively. Preliminary electrochemical studies by cyclic voltammetry of 9 and 10 show significant changes of their voltammograms upon addition of Na+. (C) 2002 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：33 / 36
页数：4
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