Nanometer-Sized Fluorous Fullerene Vesicles in Water and on Solid Surfaces

被引：53
|
作者：
Homma, Tatsuya [1 ]
Harano, Koji [1 ]
Isobe, Hiroyuki [1 ]
Nakamura, Eiichi [1 ,2 ]
机构：
[1] Univ Tokyo, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
[2] Japan Sci & Technol Agcy, Nakamura Funct Carbon Cluster Project, Exploratory Res Adv Technol ERATO, Tokyo 1130033, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 09期
关键词：
fluorine; fullerenes; self-assembly; wettability; vesicles; DELIVERY;
D O I：
10.1002/anie.200904659
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
"Chemical Equation Presented" A new twist for bucky balls: A fluorous fullerene amphiphile lacking the conventional polar head /nonpolar tail motif forms a vesicle in water (see picture, F green, C gray), mediated by the cohesive power of fullerene. The fluorous moiety covers the vesicle surface, and vesicle solutions dissolve perfluorooctane. Unlike lipid vesicles, the fluorous vesicle is very robust and retains its spherical shape even on a solid substrate under high vacuum. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1665 / 1668
页数：4
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