Trichloroethylene Transformation in Aerobic Pyrite Suspension: Pathways and Kinetic Modeling

被引：50
|
作者：
Pham, Hoa T. [1 ]
Suto, Koichi [1 ]
Inoue, Chihiro [1 ]
机构：
[1] Tohoku Univ, Grad Sch Environm Studies, Aoba Ku, Sendai, Miyagi 9808579, Japan
来源：
ENVIRONMENTAL SCIENCE & TECHNOLOGY | 2009年 / 43卷 / 17期
基金：
日本学术振兴会;
关键词：
ELECTROCHEMICAL OXIDATION; HYDROXYL RADICALS; RATE CONSTANTS; DECOMPOSITION; WATER; DECHLORINATION; ELECTRODES; MECHANISM; MINERALS; RNA;
D O I：
10.1021/es900623u
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The pathways and kinetics of trichloroethylene (TCE) degradation in aerobic pyrite suspension were investigated. The detection of hydroxyl radical in aqueous pyrite suspension suggested that TCE was degraded by this strong oxidant. The reaction pathways of TCE degradation were proposed in which the degradation of TCE to formic acid and finally to CO2 was the main route. Degradation of TCE to oxalic acid and to dichloroacetic acid were found as minor pathways. Degradation rates of TCE to formic acid, glyoxylic acid, and dichloroacetic acid were obtained using kinetic model at 1.2 x 10(-2), 9.8 X 10(-4) and 4.6 x 10(-4) h(-1), respectively.
引用
收藏
页码：6744 / 6749
页数：6
相关论文
共 50 条
  • [41] Transformation of tetracycline antibiotics with goethite: Mechanism, kinetic modeling and toxicity evaluation
    Li, Jingchen
    Zhao, Lin
    Zhang, Ruochun
    Teng, H. Henry
    Padhye, Lokesh P.
    Sun, Peizhe
    WATER RESEARCH, 2021, 199
  • [42] Kinetic modeling of methanol transformation into olefins on a SAPO-34 catalyst
    Gayubo, AG
    Aguayo, AT
    del Campo, AES
    Tarrío, AM
    Bilbao, J
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2000, 39 (02) : 292 - 300
  • [43] Gas-phase heterogeneous photocatalytic oxidation of ethanol: Pathways and kinetic modeling
    Nimlos, MR
    Wolfrum, EJ
    Brewer, ML
    Fennell, JA
    Bintner, G
    ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1996, 30 (10) : 3102 - 3110
  • [44] Mathematical formalisms based on approximated kinetic representations for modeling genetic and metabolic pathways
    Alves, Rui
    Vilaprinyo, Ester
    Hernandez-Bermejo, Benito
    Sorribas, Albert
    BIOTECHNOLOGY AND GENETIC ENGINEERING REVIEWS, VOL 25, 2008, 25 : 1 - 40
  • [45] Effective sonophotocatalytic degradation of tetracycline in water: Optimization, kinetic modeling, and degradation pathways
    V. Karim, Ansaf
    Boczkaj, Grzegorz
    Shriwastav, Amritanshu
    CHEMICAL ENGINEERING AND PROCESSING-PROCESS INTENSIFICATION, 2024, 205
  • [46] A critical study on the efficacy of kinetic sorption modeling to elucidate the effective removal pathways
    Mazlum, Sueleyman
    Mazlum, Nazire
    Kilic, Mehmet
    Keskin, Mustafa Erol
    Karakaya, Hasan
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 337 (1-3) : 185 - 193
  • [47] A kinetic modeling for carbon metabolism in sequencing batch reactor under multiple aerobic/anoxic conditions
    Fan, Ji
    Vanrolleghem, Peter A.
    Lu, Shuguang
    APPLIED MICROBIOLOGY AND BIOTECHNOLOGY, 2012, 96 (01) : 241 - 252
  • [48] A kinetic modeling for carbon metabolism in sequencing batch reactor under multiple aerobic/anoxic conditions
    Ji Fan
    Peter A. Vanrolleghem
    Shuguang Lu
    Applied Microbiology and Biotechnology, 2012, 96 : 241 - 252
  • [49] Transformation of tetramethyldisiloxane in used oil alkali treatment conditions: mechanism and kinetic modeling
    Kupareva, Antonina
    Warna, Johan
    Grenman, Henrik
    Murzin, Dmitry Yu
    JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2016, 91 (01) : 105 - 112
  • [50] STRUCTURED KINETIC MODELING OF HYBRIDOMA GROWTH AND MONOCLONAL-ANTIBODY PRODUCTION IN SUSPENSION-CULTURES
    BATT, BC
    KOMPALA, DS
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 194 : 145 - MBTD
12345