Metal-Catalyzed Asymmetric Hydrogenation of C=N Bonds

被引：87

作者：

Abdine, Racha Abed Ali ^{[1
]}

Hedouin, Gaspard ^{[1
]}

Colobert, Francoise ^{[1
]}

Wencel-Delord, Joanna ^{[1
]}

机构：

[1] Univ Haute Alsace, Univ Strasbourg, Lab Innovat Mol & Applicat, ECPM,UMR CNRS 7042, F-67087 Strasbourg, France

来源：

ACS CATALYSIS | 2021年 / 11卷 / 01期

关键词：

asymmetric hydrogenation; metal-catalysis; imine; chiral amine; ligand; HIGHLY ENANTIOSELECTIVE HYDROGENATION; PHOSPHINE-PHOSPHORAMIDITE LIGANDS; IRIDIUM COMPLEXES; TRANSITION-METAL; IMINE HYDROGENATION; CHIRAL DIPHOSPHINE; OXAZOLINE LIGANDS; CYCLIC IMINES; DIASTEREOSELECTIVE HYDROGENATION; ACYCLIC IMINES;

D O I：

10.1021/acscatal.0c03353

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This Review recaps the achievements in the field of metal-catalyzed asymmetric direct hydrogenation of nonactivated and activated imines. A summary of the reported catalytic systems with the corresponding reactivity, selectivity, and limitations is given including a discussion about the effects of some reaction conditions on the enantioselectivity of imine hydrogenation. An analysis of proposed imine hydrogenation mechanisms is discussed.

引用

页码：215 / 247

页数：33

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