Metal-Catalyzed Asymmetric Hydrogenation of C=N Bonds

被引：87
|
作者：
Abdine, Racha Abed Ali [1 ]
Hedouin, Gaspard [1 ]
Colobert, Francoise [1 ]
Wencel-Delord, Joanna [1 ]
机构：
[1] Univ Haute Alsace, Univ Strasbourg, Lab Innovat Mol & Applicat, ECPM,UMR CNRS 7042, F-67087 Strasbourg, France
来源：
ACS CATALYSIS | 2021年 / 11卷 / 01期
关键词：
asymmetric hydrogenation; metal-catalysis; imine; chiral amine; ligand; HIGHLY ENANTIOSELECTIVE HYDROGENATION; PHOSPHINE-PHOSPHORAMIDITE LIGANDS; IRIDIUM COMPLEXES; TRANSITION-METAL; IMINE HYDROGENATION; CHIRAL DIPHOSPHINE; OXAZOLINE LIGANDS; CYCLIC IMINES; DIASTEREOSELECTIVE HYDROGENATION; ACYCLIC IMINES;
D O I：
10.1021/acscatal.0c03353
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This Review recaps the achievements in the field of metal-catalyzed asymmetric direct hydrogenation of nonactivated and activated imines. A summary of the reported catalytic systems with the corresponding reactivity, selectivity, and limitations is given including a discussion about the effects of some reaction conditions on the enantioselectivity of imine hydrogenation. An analysis of proposed imine hydrogenation mechanisms is discussed.
引用
收藏
页码：215 / 247
页数：33
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