Effect of maximum amount of charge a compact star can hold, is studied here. We analyze the different features in the renewed stellar structure and discuss the reasons why such huge charge is possible inside a compact star. We studied a particular case of a polytropic equation of state (EOS) assuming the charge density is proportional to the mass density. Although the global balance of force allows a huge charge, the electric repulsion faced by each charged particle forces it to leave the star, resulting in the secondary collapse of the system to form a charged black hole.