Synthesis of new graft copolymers by combining the DPE technique and cationic polymerization

被引：0
|
作者：
Wieland, PC [1 ]
Schäfer, M [1 ]
Nuyken, O [1 ]
机构：
[1] Tech Univ Munich, Lehrstuhl Makromol Stoffe, D-85747 Garching, Germany
来源：
MACROMOLECULAR RAPID COMMUNICATIONS | 2002年 / 23卷 / 14期
关键词：
block copolymers; 4-chloromethylstyrene; DPE system; graft copolymers; radical polymerization;
D O I：
10.1002/1521-3927(20021001)23:14<809::AID-MARC809>3.0.CO;2-D
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The synthesis of a new macroinitiator for cationic polymerization via radical polymerization is presented. The macroinitiator, consisting of poly(methyl methacrylate)-block-poly[styrene-co-(4-chloromethylstyrene)], was synthesized by heating poly(methyl methacrylate), prepared in the presence of 1,1-diphenylethylene, in a mixture of styrene and 4-chloromethylstyrene to 85 degreesC without any additional initiator. The resulting macroinitiator could be used for the catonic polymerization of isobutylene yielding graft copolymers.
引用
收藏
页码：809 / 813
页数：5
相关论文
共 50 条
  • [21] Synthesis of block copolymers by transformation of photosensitized cationic polymerization to stable free radical polymerization
    Yildirim, TG
    Hepuzer, Y
    Hizal, G
    Yagci, Y
    POLYMER, 1999, 40 (13) : 3885 - 3890
  • [22] Synthesis of poly(epichlorohydrin-g-methyl methacrylate) graft copolymers by the combination of cationic and atom transfer radical polymerization
    Cakmak, Ismail
    Baykara, Haci
    Journal of Applied Polymer Science, 2006, 102 (03): : 2725 - 2729
  • [23] The Synthesis of PHA-g-(PTHF-b-PMMA) Multiblock/Graft Copolymers by Combination of Cationic and Radical Polymerization
    Macit, Huelya
    Hazer, Baki
    Arslan, Huelya
    Noda, Isao
    JOURNAL OF APPLIED POLYMER SCIENCE, 2009, 111 (05) : 2308 - 2317
  • [24] Synthesis of block copolymers by the transformation of cationic polymerization into reversible atom transfer radical polymerization
    Cianga, I
    Hepuzer, Y
    Serhatli, E
    Yagci, Y
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2002, 40 (13) : 2199 - 2208
  • [25] Synthesis of poly(styrene-co-isopropenyl acetate) -g-polyisobutylene graft copolymers via combination of radical polymerization with cationic polymerization
    Ma, Wen-yan
    Wu, Yi-xian
    Feng, Li
    Xu, Ri-wei
    POLYMER, 2012, 53 (15) : 3185 - 3193
  • [26] FREE-RADICAL POLYMERIZATION - THE SYNTHESIS OF GRAFT-COPOLYMERS
    CORNER, T
    ADVANCES IN POLYMER SCIENCE, 1984, 62 : 95 - 142
  • [27] Synthesis of cellulosic graft copolymers by atom transfer radical polymerization
    Ikeda, I
    Higuchi, T
    Maeda, Y
    SEN-I GAKKAISHI, 2002, 58 (08) : 308 - 313
  • [28] Synthesis of poly(epichlorohydrin-g-methyl methacrylate) graft copolymers by the combination of cationic and atom transfer radical polymerization
    Cakmak, Ismail
    Baykara, Haci
    JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (03) : 2725 - 2729
  • [29] GRAFT POLYMERIZATION WITH CATIONIC CATALYSTS
    PLESCH, PH
    CHEMISTRY & INDUSTRY, 1958, (30) : 954 - 954
  • [30] Cationic graft polymerization lithography
    Johnson, HF
    Ozair, SN
    Jamieson, A
    Trinque, BC
    Brodsky, CC
    Willson, CG
    EMERGING LITHOGRAPHIC TECHNOLOGIES VII, PTS 1 AND 2, 2003, 5037 : 943 - 951
12345