Catalytic Water Oxidation by Single-Site Ruthenium Catalysts

被引：273
|
作者：
Concepcion, Javier J. [1 ]
Jurss, Jonah W. [1 ]
Norris, Michael R. [1 ]
Chen, Zuofeng [1 ]
Templeton, Joseph L. [1 ]
Meyer, Thomas J. [1 ]
机构：
[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA
来源：
INORGANIC CHEMISTRY | 2010年 / 49卷 / 04期
关键词：
COUPLED ELECTRON-TRANSFER; POLYPYRIDYL COMPLEXES; AQUEOUS-MEDIA; OSMIUM; REDOX;
D O I：
10.1021/ic901437e
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of monomeric ruthenium polypyridyl complexes have been synthesized and characterized, and their performance as water oxidation catalysts has been evaluated. The diversity of ligand environments and how they influence rates and reaction thermodynamics create a platform for catalyst design with controllable reactivity based on ligand variations.
引用
收藏
页码：1277 / 1279
页数：3
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