Synthesis and crystal structure of [C(NMe2)3]2[(CO)4Fe(μ-InCl2)2Fe(CO)4]

被引：0
|
作者：
Petz, W [1 ]
Weller, F [1 ]
机构：
[1] Univ Marburg, Fachbereich Chem, D-35032 Marburg, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2002年 / 628卷 / 13期
关键词：
indium iron compound; ironcarbonyl; indium chloride; crystal structure;
D O I：
10.1002/1521-3749(200213)628:13<2825::AID-ZAAC2825>3.0.CO;2-Z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of [C(NMe2)(3)](2)[(CO)(4)FeInCl3] (1) with hot water produces the dinuclear complex [C(NMe2)(3)](2)[(CO)(4)Fe(muInCl(2))(2)Fe(CO)(4)] (2) which could be crystallized from dichloromethane/pentane. 2 crystallizes in the monoclinic space group P2(1)/n with a = 835.7(1), b = 1187.8(1), c = 1902.7(1) pm, beta = 91.877(5)degrees and Z = 2. The anion contains a four-membered Fe-In-Fe-In ring with octahedral environment at the iron atom and tetrahedral coordination at the In atom.
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页码：2825 / 2826
页数：2
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