Hydrothermal Synthesis of Novel Cu(II) Material Framework

被引：1
|
作者：
Wu, Jian [1 ]
机构：
[1] Guangxi Univ Nationalities, Coll Chem & Ecol Engn, Guangxi 530006, Peoples R China
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC METAL-ORGANIC AND NANO-METAL CHEMISTRY | 2009年 / 39卷 / 09期
关键词：
Cu(II) polymer; porous material; rigid ligand; crystal structure; METAL-ORGANIC FRAMEWORKS; COORDINATION POLYMERS; DIPICOLINIC ACID; LIGANDS;
D O I：
10.1080/15533170903327901
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new porous coordination polymer [Cu(bpt)(pydc)] n center dot 2nCHCl3 center dot nH2O (1) (bpt = 2,5-bis(4-pyridyl)-1,3,4-thiadiazole and H2pydc = pyridine-2,6-dicarboxylic acid) was synthesized by hydrothermal reaction and and characterized by elemental analysis, IR and X-ray diffraction. The center Cu(II) in complex 1 is linked by rigid pydc and bpt ligands to form square-grid-like corrugated sheets. The adjacent sheets are displaced by about one half of the polymer period along the direction of extension and stacked with iterative sequence of ABAB fashion.
引用
收藏
页码：566 / 569
页数：4
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