Alternative modification methods for sol-gel coatings of silica, titania and silica-titania using ultraviolet irradiation and water vapor

被引:0
|
作者
Imai, H [1 ]
Hirashima, H [1 ]
Awazu, K [1 ]
机构
[1] Keio Univ, Fac Sci & Technol, Kohoku Ku, Yokohama, Kanagawa 2238522, Japan
来源
2ND INTERNATIONAL CONFERENCE ON COATINGS ON GLASS, ICCG: HIGH-PERFORMANCE COATINGS FOR TRANSPARENT SYSTEMS IN LARGE-AREA AND/OR HIGH-VOLUME APPLICATIONS | 1999年
关键词
silicon oxide; ttitanium oxide; laser irradiation; water;
D O I
暂无
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We investigated relatively new techniques for densification and crystallization of sol-gel silica, titania and silica-titania coatings at relatively low temperatures. irradiation of ultraviolet photons above the hand-gap energy was found to lead shrinkage of the sol-gel films through electronic excitations. Crystallization of sol-gel titania coatings was achieved by irradiation of ultraviolet laser (4.7 eV) beam. Exposure to water vapor was shown to he effective in rearrangement of sol-gel films causing densification of silica, crystallization of titania and phase separation of silica-titania around 100 degrees C. These techniques are useful for preparation of hard silica coatings and crystalline titania films on low-heat-resistant substrates, such as polymer prates.
引用
收藏
页码:160 / 163
页数:4
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