Di-μ-methoxo-bis{[bis(methoxycarbimido)aminato]copper(II)}

被引:5
|
作者
Zhao, Xiao-Hu [1 ]
Chen, Xu-Dong [1 ]
Du, Miao [1 ]
机构
[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China
关键词
single-crystal X-ray study; T=298 K; mean sigma(N-C)=0.005 angstrom; R factor=0.045; wR factor=0.117; data-to-parameter ratio=13.2;
D O I
10.1107/S1600536806050483
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the centrosymmetric dinuclear title complex, [Cu-2(CH3O)(2)-(C4H8N3O2)(2)], the two Cu-II ions are linked by a pair of methoxide bridges, with a non-bonding Cu center dot center dot center dot Cu distance of 3.048 (1) angstrom. Each Cu-II center adopts a CuO2N2 square-planar geometry, coordinated by the bidentate bis(methoxycarbimido) aminate and two methoxide ligands.
引用
收藏
页码:M3580 / M3581
页数:2
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