Di-μ-methoxo-bis{[bis(methoxycarbimido)aminato]copper(II)}

被引:5
|
作者
Zhao, Xiao-Hu [1 ]
Chen, Xu-Dong [1 ]
Du, Miao [1 ]
机构
[1] Tianjin Normal Univ, Coll Chem & Life Sci, Tianjin 300074, Peoples R China
关键词
single-crystal X-ray study; T=298 K; mean sigma(N-C)=0.005 angstrom; R factor=0.045; wR factor=0.117; data-to-parameter ratio=13.2;
D O I
10.1107/S1600536806050483
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the centrosymmetric dinuclear title complex, [Cu-2(CH3O)(2)-(C4H8N3O2)(2)], the two Cu-II ions are linked by a pair of methoxide bridges, with a non-bonding Cu center dot center dot center dot Cu distance of 3.048 (1) angstrom. Each Cu-II center adopts a CuO2N2 square-planar geometry, coordinated by the bidentate bis(methoxycarbimido) aminate and two methoxide ligands.
引用
收藏
页码:M3580 / M3581
页数:2
相关论文
共 50 条
  • [1] Di-μ-methoxo-bis[dipyridinecopper(II)] diperchlorate
    Wang, J
    Tong, ML
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : M1223 - M1224
  • [2] Di-μ-methoxo-bis[aquadimethoxo-nitrosylmolybdenum(II)]
    Bucher, Jolanta
    Blacque, Olivier
    Berke, Heinz
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : M2935 - U725
  • [3] Electronic structure of Bis{bis(methoxycarbimido)aminato}-copper(II) complex
    Fronc, Marek
    Herich, Peter
    Kozisek, Jozef
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2011, 67 : C452 - C453
  • [4] MAGNETIC-SUSCEPTIBILITY OF BIS[BIS(METHOXYCARBIMIDO)AMINATO]COPPER(II) COMPLEX
    BOCA, R
    BARAN, P
    DLHAN, L
    CHEMICAL PAPERS, 1994, 48 (03) : 177 - 181
  • [5] Bis[bis(methoxycarbimido)aminato]copper(II) 1-methylpyrrolidin-2-one disolvate
    Chippindale, Ann M.
    Bilbe, Edward J.
    Hibble, Simon J.
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2009, 65 : M485 - M487
  • [6] Di-μ-methoxo-bis({N,N′-bis[2-(3,5-dimethylpyrazol-1-yl)ethyl]amine-κ3N}copper(II)) bis(hexafluorophosphate)
    Kim, JH
    Roh, SG
    Jeong, JH
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : E543 - E544
  • [7] Synthesis and catalytic activity of DI-μ-methoxo-bis[(2-aminopyridine)(chloro)copper(II)] and m-xylylenediamine Zn(OAc)2
    Mei, L.
    Tai, L. S.
    Li, J.
    Tao, F. H.
    Liang, L. X.
    Zhong, Y. S.
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2011, 37 (02) : 153 - 159
  • [8] Synthesis and catalytic activity of DI-μ-methoxo-bis[(2-aminopyridine)(chloro)copper(II)] and m-xylylenediamine Zn(OAc)2
    L. Mei
    L. S. Tai
    J. Li
    F. H. Tao
    L. X. Liang
    Y. S. Zhong
    Russian Journal of Coordination Chemistry, 2011, 37 : 153 - 159
  • [9] Activation of the carbon beta-site in nonlinear pseudohalides by coordination. Crystal, molecular, and electronic structure of a bis{bis(methoxycarbimido)aminato}copper(II) complex
    Boca, R
    Hvastijova, M
    Kozisek, J
    Valko, M
    INORGANIC CHEMISTRY, 1996, 35 (16) : 4794 - 4797
  • [10] Di-μ-methoxo-bis{[diacetyl monooxime (4-methoxybenzoyl)hydrazonato-κ3O,N,N′]oxovanadium(V)}
    Deng, ZP
    Gao, S
    Huo, LH
    Zhao, H
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2005, 61 : M2214 - M2216