Novel two-dimensional molecular space material with regular double bonds

The development of a novel two-dimensional molecular space material with regular double bonds was described. A layered acrylamidephenylsilica (AAPhS) was synthesized by adding 1.303 mL of acrylic acid to a mixture of 0.168 g of aminophenylsilica material (APhTMS-Cl) and 84 mL of deionized water. It was found by employing solid-state 13C NMR, the IR spectrum, and the XRD patterns that layered AAPhS had functional regular double bonds and a stable layer structure. It was also found by employing elemental analysis that the amino groups in layered APhTMS-Cl were transformed to amide and the double bonds were regularly arranged in the layer structure of layered AAPhS. The results show that novel two-dimensional molecular reaction space with regular double bonds can be used as a functional molecular reaction space by utilization of the functionality of regular double bonds.