Rational Optimization of Benzo[2,1-b;3,4-b′]dithilophene-Containing Polymers for Organic Field-Effect Transistors

被引:72
|
作者
Rieger, Ralph [1 ]
Beckmann, Dirk [1 ]
Pisula, Wojciech [1 ]
Steffen, Werner [1 ]
Kastler, Marcel [1 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
关键词
THIN-FILM TRANSISTORS; CHARGE-TRANSPORT PROPERTIES; POLYTHIOPHENE; SEMICONDUCTORS; MOBILITY; NANOPARTICLES; MORPHOLOGY;
D O I
10.1002/adma.200901286
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The rational structure optimization of a polythiophene containing benzo[2,1b;3,4-b']dithiophene on the molecular level leads to a polymer that is easily synthesized and processed. Fabricated on a flexible substrate, the polymer shows excellent device characteristics, good reproducibility, and charge-carrier mobilities up to 0.5 cm(2) V-1 s(-1) without annealing.
引用
收藏
页码:83 / +
页数:5
相关论文
共 50 条
  • [31] Effect of fluorine substitution on naphtho[2,1-b:3,4-b′]bis [1]-benzothiophene-derived semiconductors for transistor application
    Li, Zhaoguang
    Zhang, Ji
    Zhang, Weifeng
    Guo, Lei
    Huang, Jianyao
    Yu, Gui
    Wong, Man Shing
    ORGANIC ELECTRONICS, 2016, 32 : 47 - 53
  • [32] The Effect of Ring Expansion in Thienobenzo[b]indacenodithiophene Polymers for Organic Field-Effect Transistors
    Chen, Hu
    Wadsworth, Andrew
    Ma, Chun
    Nanni, Alice
    Zhang, Weimin
    Nikolka, Mark
    Luci, Alexander M. T.
    Perdigao, Luis M. A.
    Thorley, Karl J.
    Cendra, Camila
    Larson, Bryon
    Rumbles, Garry
    Anthopoulos, Thomas D.
    Salleo, Alberto
    Costantini, Giovanni
    Sirringhaus, Henning
    McCulloch, Iain
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2019, 141 (47) : 18806 - 18813
  • [33] New Non-Fullerene Acceptor with Extended Conjugation of Cyclopenta cyclopenta [2,1-b:3,4-b′] Dithiophene for Organic Solar Cells
    Sun, Cheng
    Lee, Sanseong
    Choi, Changeun
    Jeong, Soyeong
    Oh, Juhui
    Kim, Ju-Hyeon
    Kim, Jaeyoung
    Baek, Ho Eon
    Kang, Hongkyu
    Jang, Soo-Young
    Choi, Hyun Ho
    Lee, Kwanghee
    Kim, Yun-Hi
    MOLECULES, 2022, 27 (21):
  • [34] Effect of hexadecyl groups in 4 position on the electrochemical polymerisation of 4H-cyclopenta[2,1-b:3,4-b′]dithiophene
    Casalbore-Miceli, G
    Camaioni, N
    Geri, A
    Cristani, M
    Fichera, AM
    Berlin, A
    SYNTHETIC METALS, 2000, 108 (01) : 47 - 56
  • [35] Syntheses and transformations of azeto[2,1-a]- and -[2,1-b]isoquinolines and azeto[1′,2′:1,2]pyrido[3,4-b]indoles
    Fülöp, F
    Bernáth, G
    CURRENT ORGANIC CHEMISTRY, 1999, 3 (01) : 1 - 24
  • [36] Synthesis of a quinoidal dithieno[2,3-d;2′,3′-d]benzo[2,1-b;3,4-b′]-dithiophene based open-shell singlet biradicaloid
    Xia, Debin
    Keerthi, Ashok
    An, Cunbin
    Baumgarten, Martin
    ORGANIC CHEMISTRY FRONTIERS, 2017, 4 (01): : 18 - 21
  • [37] Δ4,4′-dicyclopenta[2,1-b:3,4-b′]dithiophene.: A conjugated bridging unit for low band gap conducting polymers
    Loganathan, K
    Cammisa, EG
    Myron, BD
    Pickup, PG
    CHEMISTRY OF MATERIALS, 2003, 15 (09) : 1918 - 1923
  • [38] Electrosynthesis and characterization of a novel electrochromic copolymer of N-methylpyrrole with cyclopenta[2,1-b:3,4-b′]dithiophene
    Yunzhi Fu
    Xinfeng Cheng
    Jinsheng Zhao
    Tianyu Kong
    Chuansheng Cui
    Xianxi Zhang
    Polymer Journal, 2012, 44 : 1048 - 1055
  • [39] Ambipolar Single Crystal Organic Field-effect Transistors Based on (4,4′-Diphenyl)dinaphtho [2,1-b:2′,1′-f]thieno[3,2-b]thiophene
    Kunugi, Yoshihito
    Arakawa, Teppei
    Tsutsui, Masanori
    Okamoto, Kazuo
    JOURNAL OF PHOTOPOLYMER SCIENCE AND TECHNOLOGY, 2012, 25 (03) : 285 - 288
  • [40] Highly efficient and facile alkylation of 4H-cyclopenta-[2,1-b:3,4-b′]dithiophene in water
    Iyer, Parameswar Krishnan (pki@iitg.ernet.in), 1600, Royal Society of Chemistry (40):