Oxidation of 3,4-dihydropyrimidin-2(1H)-ones with nitrosonium (NO+)

被引：10
|
作者：
Liang, Rui Rui [1 ]
Wu, Guai Li [1 ]
Wu, Wen Tao [1 ]
Wu, Long Min [1 ]
机构：
[1] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Peoples R China
来源：
CHINESE CHEMICAL LETTERS | 2009年 / 20卷 / 10期
基金：
中国国家自然科学基金;
关键词：
Dihydropyrimidinone; Nitrosonium; Oxidation; PHENYL 2,4,6-TRINITROPHENYL ETHER; AROMATIC-SUBSTITUTION REACTIONS; NONPOLAR APROTIC-SOLVENT; SOLID-PHASE SYNTHESIS; NITRIC-OXIDE; HANTZSCH 1,4-DIHYDROPYRIDINES; ELECTROCHEMICAL OXIDATION; PYRIMIDINE; BIGINELLI; DIHYDROPYRIMIDINONES;
D O I：
10.1016/j.cclet.2009.04.039
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
3, 4-Dihydropyrimidin-2(1H)-ones (DHPMs) were oxidized with 1.2 equiv. of nitrosonium tetrafluoroborate (NO+BF4-) to pyrimidin-2(1H)-ones in acetonitrile at room temperature in high yields. (C) 2009 Long Min Wu. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：1183 / 1186
页数：4
相关论文
共 50 条
  • [1] Oxidation of 3,4-dihydropyrimidin-2(1H)-ones with nitrosonium(NO~+)
    Rui Rui Liang
    Chinese Chemical Letters, 2009, 20 (10) : 1183 - 1186
  • [2] Microwave-assisted Oxidation of 3,4-Dihydropyrimidin-2(1H)-ones
    Memarian, Hamid Reza
    Sabzyan, Hassan
    Farhadi, Asadollah
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2009, 64 (05): : 532 - 540
  • [3] Facile aromatization of 3,4-dihydropyrimidin-2(1H)-ones(DHPMs) by iodine
    Manisha M.Kodape
    Anand S.Aswar
    Nandkishor D.Gawhale
    Vivek T.Humne
    Bilal Ahmad Mir
    ChineseChemicalLetters, 2012, 23 (12) : 1339 - 1342
  • [4] Heteropoly acid catalyzed synthesis of 3,4-dihydropyrimidin-2(1H)-ones
    Maradur, Sanjeev P.
    Gokavi, Gavisiddappa S.
    CATALYSIS COMMUNICATIONS, 2007, 8 (03) : 279 - 284
  • [5] Light-induced dehydrogenation of 3,4-dihydropyrimidin-2(1H)-ones
    Hamid Reza Memarian
    Asadollah Farhadi
    Monatshefte für Chemie - Chemical Monthly, 2009, 140 : 1217 - 1220
  • [6] α-Chlorobenzyl Isocyanates in a New Synthesis of 3,4-Dihydropyrimidin-2(1H)-ones
    M.V. Vovk
    V.A. Sukach
    Russian Journal of Organic Chemistry, 2005, 41 : 1240 - 1241
  • [7] DFT study of the molecular structure of 3,4-dihydropyrimidin-2(1H)-ones
    Memarian, Hamid Reza
    Sabzyan, Hassan
    Farhadi, Asadollah
    MONATSHEFTE FUR CHEMIE, 2010, 141 (11): : 1203 - 1212
  • [8] Photo-oxidation of 5-acetyl-3,4-dihydropyrimidin-2(1H)-ones
    Memarian, Hamid Reza
    Farhadi, Asadollah
    Sabzyan, Hassan
    Soleymani, Mousa
    JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2010, 209 (2-3) : 95 - 103
  • [9] Efficient synthesis of 3,4-dihydropyrimidin-2(1H)-ones by aluminum hydrogensulfate
    Khodaei, MM
    Salehi, P
    Zolfigol, MA
    Sirouszadeh, S
    POLISH JOURNAL OF CHEMISTRY, 2004, 78 (03) : 385 - 388
  • [10] Light-induced dehydrogenation of 3,4-dihydropyrimidin-2(1H)-ones
    Memarian, Hamid Reza
    Farhadi, Asadollah
    MONATSHEFTE FUR CHEMIE, 2009, 140 (10): : 1217 - 1220
12345