Coordination preference of Ga in hydrides

被引：1

作者：

Klaveness, A. ^{[1
]}

Swang, O.

Kjekshus, A.

Fjellvag, H.

机构：

[1] Univ Oslo, Dept Chem, Oslo, Norway

[2] SINTEF Mat & Chem, Oslo, Norway

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 26期

关键词：

D O I：

10.1021/ic0616232

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Aluminum and gallium show some interesting differences in their coordination chemistry. Solid GaH3 is unknown, in contrast to solid AlH3. Ga equivalents of Li3AlH6, Na3AlH6, and other hydrides whose structure contain AlH63- ions, are unknown. We relate these differences to an instability of the hexacoordinated gallium moiety.

引用

页码：10698 / 10701

页数：4

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