Tetrathiafulvalenes in macrocyclic and supramolecular chemistry

被引：38
|
作者：
Becher, J
Li, ZT
Blanchard, P
Svenstrup, N
Lau, J
Nielsen, MB
Leriche, P
机构：
[1] Department of Chemistry, Odense University
来源：
PURE AND APPLIED CHEMISTRY | 1997年 / 69卷 / 03期
关键词：
D O I：
10.1351/pac199769030465
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We describe that use of a stepvise selective protection-deprotection of tetrathiafulvalene (TTF)-thiolates give rise to either two or three-dimensional macrobicyclic tetrathiafulvalenophanes in high yields by convergent syntheses. Configurationally selective self-assembly of cyclic or bicyclic tetrathiafulvalenes using the cyclic pi-acceptor cyclo-bis(paraquat-p-phenylene) yields [2]- or [3]pseudocatenanes.
引用
收藏
页码：465 / 470
页数：6
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