Synthesis and Diels-Alder cycloaddition reaction of norbornadiene and benzonorbornadiene dimers

被引:5
|
作者
Nisanci, Bilal [1 ]
Dalkilic, Erdin [1 ]
Guney, Murat [1 ]
Dastan, Arif [1 ]
机构
[1] Ataturk Univ, Fac Sci, Dept Chem, TR-25240 Erzurum, Turkey
关键词
benzonorbornadiene; Diels-Alder reaction; norbornadiene; Stille coupling; HIGH-TEMPERATURE BROMINATION; DERIVATIVES; DIENES;
D O I
10.3762/bjoc.5.39
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Dimeric forms of norbornadiene and benzonorbornadiene were synthesized starting with known monobromide derivatives. The Diels-Alder cycloaddition reaction of dimers with TCNE and PTAD was investigated and new norbornenoid polycyclics were obtained. All compounds were characterized properly using NMR spectroscopy.
引用
收藏
页数:6
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