Delivering carbide ligands to sulfide-rich clusters

被引：28

作者：

Reinholdt, Anders ^{[1
]}

Herbst, Konrad ^{[2
]}

Bendix, Jesper ^{[1
]}

机构：

[1] Univ Copenhagen, Dept Chem, Univ Pk 5, DK-2100 Copenhagen, Denmark

[2] Haldor Topsoe Res Labs, Haldor Topsoes Alle 1, DK-2800 Lyngby, Denmark

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 10期

关键词：

OLEFIN METATHESIS REACTIONS; NITROGENASE FEMO COFACTOR; INTERSTITIAL CARBIDE; CRYSTAL-STRUCTURES; BRIDGED COMPLEXES; CARBON-MONOXIDE; ATOM-TRANSFER; RUTHENIUM; IRON; CUBANE;

D O I：

10.1039/c5cc08918b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The propensity of the terminal ruthenium carbide Ru(C)Cl-2(PCy3)(2)(RuC) to form carbide bridges to electron-rich transition metals enables synthetic routes to metal clusters with coexisting carbide and sulfide ligands. Electrochemical experiments show the RuRC ligand to exert a relatively large electron-withdrawing effect compared with PPh3, effectively shifting redox potentials.

引用

页码：2015 / 2018

页数：4

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