Pyrolysis mass spectrometry analysis of polycarbonate/poly(methyl methacrylate)/poly(vinyl acetate) ternary blends

Direct insertion probe pyrolysis mass spectrometry (DIP-MS) analyses of polycarbonate/poly(methyl methacrylate)/poly(vinyl acetate), (PC/PMMA/PVAc), ternary blends have been performed. The PC/PMMA/PVAc ternary blends were obtained by coalescing from their common gamma-cyclodextrin-inclusion compounds (CD-ICs), through the removal of the gamma-CD, host (coalesced blend), and by a co-precipitation method (physical blend). The coalesced ternary blend showed different thermal behaviors compared to the co-precipitated physical blend. The stability of PC chains decreased due to the reactions of CH3COOH formed by deacetylation of PVAc above 300 degrees C, for both coalesced and physical blends. This process was more effective for the physical blend most likely due to the enhanced diffusion of CH3COOH into the amorphous PC domains, where it can further react producing low molecular weight PC fragments hearing methyl carbonate chain ends. The decrease in thermal stability of PC chains was less significant for the coalesced ternary blend indicating that the diffusion of CH3COOH was either somewhat limited or competed with intermolecular reactions between PMMA and PC and between PMMA and PVAc, which were detected and were associated with their close proximity in the intimately mixed coalesced PC/PMMA/PVAc ternary blend. (c) 2006 Elsevier Ltd. All rights reserved.