A mass spectrometric study of the thermodynamic properties of Al2O3-SiO2 melts

被引：0
|
作者：
Shornikov, SI [1 ]
Archakov, IY [1 ]
机构：
[1] Russian Acad Sci, IV Grebenshchikov Silicate Chem Inst, St Petersburg 199155, Russia
来源：
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY | 2000年 / 74卷 / 05期
关键词：
D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The Knudsen effusion method with mass spectrometric analysis of vaporization products was used to study the thermodynamic properties of Al2O3-SiO2 melts in wide concentration and temperature ranges. The obtained concentration dependence of the Gibbs energy of formation of melts in the Al2O3-SiO2 system is indicative of negative deviations from ideality. The activities of Al2O3 and SiO2 determined experimentally are in satisfactory agreement with the results obtained in Monte Carlo calculations and in the approximation of the ideal associated solution model of complex phases.
引用
收藏
页码：684 / 688
页数：5
相关论文
共 50 条
  • [31] Mass Spectrometric Study of the Thermodynamic Properties of Melts in the Rb2O–B2O3 System
    V. L. Stolyarova
    S. I. Lopatin
    Glass Physics and Chemistry, 2004, 30 : 151 - 156
  • [32] Mass spectrometric study of the thermodynamic properties of melts in the Rb2O-B2O-B2O3 system
    Stolyarova, VL
    Lopatin, SI
    GLASS PHYSICS AND CHEMISTRY, 2004, 30 (02) : 151 - 156
  • [33] Mass Spectrometric Study of the Thermodynamic Properties of Melts in the CaO–TiO2–SiO2 System
    V. L. Stolyarova
    D. O. Zhegalin
    S. V. Stolyar
    Glass Physics and Chemistry, 2004, 30 : 142 - 150
  • [34] Mass spectrometric investigation of the thermodynamic properties of glass melts in the Cs2O-B2O3-SiO2 system at high temperatures
    Stolyarova, V. L.
    Lopatin, S. I.
    Plotnikov, E. N.
    GLASS PHYSICS AND CHEMISTRY, 2006, 32 (05) : 543 - 549
  • [35] Mass spectrometric investigation of the thermodynamic properties of glass melts in the Cs2O-B2O3-SiO2 system at high temperatures
    V. L. Stolyarova
    S. I. Lopatin
    E. N. Plotnikov
    Glass Physics and Chemistry, 2006, 32 : 543 - 549
  • [36] High-temperature mass spectrometric study of thermodynamic properties in the TiO2-Al2O3-SiO2 system and modeling
    Stolyarova, Valentina L.
    Vorozhtcov, Viktor A.
    Shemchuk, Daria, V
    Shilov, Andrey L.
    Lopatin, Sergey, I
    Almjashev, Vyacheslav, I
    Shuvaeva, Elena B.
    Kirillova, Svetlana A.
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2022, 36 (19)
  • [37] Thermodynamic analysis of the metastable regions for the Al2O3-SiO2 system
    Djuric, M
    Mihajlov, A
    PetrasinovicStojkanovic, L
    Zivanovic, B
    JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1996, 79 (05) : 1252 - 1256
  • [38] Study on the NaNp/Al2O3-SiO2 system
    Maksimowski, P
    Skupinski, W
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 292 (01) : 152 - 159
  • [39] Al2O3-SiO2 aerogel reinforced with aluminum silicate nanofibers: a strategy to preserve the properties of Al2O3-SiO2 aerogel
    Mingyuan Hao
    Huanle Chen
    Chenkang Xia
    Teng Su
    Chao Ma
    Yang Miao
    Journal of Sol-Gel Science and Technology, 2024, 109 : 523 - 533
  • [40] High-temperature mass spectrometric study of the vaporization processes and thermodynamic properties of melts in the PbO-B2O3-SiO2 system
    Stolyarova, V. L.
    Lopatin, S. I.
    Shilov, A. L.
    Shugurov, S. M.
    RAPID COMMUNICATIONS IN MASS SPECTROMETRY, 2013, 27 (13) : 1559 - 1566
12345