Ruthenium Catalyzed C-H Selenylations of Aryl Acetic Amides and Esters via Weak Coordination

被引：25

作者：

Weng, Zhengyun ^{[1
]}

Fang, Xinyue ^{[1
]}

He, Meicui ^{[1
]}

Gu, Linghui ^{[1
]}

Lin, Jiafu ^{[1
]}

Li, Zheyu ^{[1
]}

Ma, Wenbo ^{[1
]}

机构：

[1] Chengdu Univ, Sichuan Ind Inst Antibiot, Antibiot Res & Reevaluat Key Lab Sichuan Prov, Chengdu 610052, Sichuan, Peoples R China

来源：

ORGANIC LETTERS | 2019年 / 21卷 / 16期

关键词：

LATE-STAGE DIVERSIFICATION; ALPHA-OXOCARBOXYLIC ACIDS; BOND ACTIVATION; ARENES; CHALCOGENATION; DERIVATIVES; FUNCTIONALIZATION; PHENYLACETAMIDES; ARYLACETAMIDES; OLEFINATION;

D O I：

10.1021/acs.orglett.9b02196

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient ruthenium-catalyzed direct C-H selenylation of aryl acetic amides and esters has been achieved via distal weakly coordination. Notable features of this protocol including broad substrate scope, wide functional group tolerance, and good regioselectivity. In addition, diaryl disulfides were also successfully applied to this reaction under slightly modified conditions.

引用

页码：6310 / 6314

页数：5

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