Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2 or Air

被引：380
|
作者：
Zhang, Yang-Hui [1 ]
Yu, Jin-Quan [1 ]
机构：
[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 41期
基金：
美国国家科学基金会;
关键词：
C-H BONDS; OXYGEN INSERTION; OXIDATION; BENZOQUINONE; ACTIVATION; PEROXIDES; COMPLEXES; MECHANISM; DIOXYGEN; METHANOL;
D O I：
10.1021/ja907198n
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Pd(II)-catalyzed ortho-hydroxylation of variously substituted benzoic acids under 1 atm of O-2 or air is achieved under nonacidic conditions. Extensive labeling studies support a direct oxygenation of aryl C-H bonds with molecular oxygen.
引用
收藏
页码：14654 / +
页数：3
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