Pd(II)-Catalyzed Hydroxylation of Arenes with 1 atm of O2 or Air

被引：380

作者：

Zhang, Yang-Hui ^{[1
]}

Yu, Jin-Quan ^{[1
]}

机构：

[1] Scripps Res Inst, Dept Chem, La Jolla, CA 92037 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 41期

基金：

美国国家科学基金会;

关键词：

C-H BONDS; OXYGEN INSERTION; OXIDATION; BENZOQUINONE; ACTIVATION; PEROXIDES; COMPLEXES; MECHANISM; DIOXYGEN; METHANOL;

D O I：

10.1021/ja907198n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Pd(II)-catalyzed ortho-hydroxylation of variously substituted benzoic acids under 1 atm of O-2 or air is achieved under nonacidic conditions. Extensive labeling studies support a direct oxygenation of aryl C-H bonds with molecular oxygen.

引用

页码：14654 / +

页数：3

共 50 条

[1] Direct hydroxylation of arenes with O2 catalyzed by V@CN catalyst
Li, Yan
Li, Bing
Chen, Ting
Zhou, Zhicheng
Wang, Jun
Huang, Jun
CHINESE JOURNAL OF CATALYSIS, 2015, 36 (07) : 1086 - 1092
[2] Phosphonation of arenes with dialkyl phosphites catalyzed by Mn(II)/CO(II)/O2 redox couple
Kagayama, T
Nakano, A
Sakaguchi, S
Ishii, Y
ORGANIC LETTERS, 2006, 8 (03) : 407 - 409
[3] Pd(II) or Pt(II)-catalyzed hydroarylation of alkynes by arenes
Jia, CG
Kitamura, T
Fujiwara, Y
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2001, 59 (11) : 1052 - 1061
[4] Pd(II) catalyzed acetoxylation of arenes with iodosyl acetate
Yoneyama, T
Crabtree, RH
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 1996, 108 (01) : 35 - 40
[5] Rhodium-Catalyzed Regioselective Hydroxylation of Cage B-H Bonds of o-Carboranes with O2 or Air
Lyu, Hairong
Quan, Yangjian
Xie, Zuowei
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2016, 55 (39) : 11840 - 11844
[6] Intermolecular Oxidative Amination of Olefins with Amines Catalyzed by the Pd(II)/NPMoV/O2 System
Obora, Yasushi
Shimizu, Yosuke
Ishii, Yasutaka
ORGANIC LETTERS, 2009, 11 (21) : 5058 - 5061
[7] Regioselective copper-catalyzed chlorination and bromination of arenes with O2 as the oxidant
Yang, Lujuan
Lu, Zhan
Stahl, Shannon S.
CHEMICAL COMMUNICATIONS, 2009, (42) : 6460 - 6462
[8] Ru-catalyzed oxidative coupling of arenes with olefins using O2
Weissman, H
Song, XP
Milstein, D
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (02) : 337 - 338
[9] PHASE EQUILIBRIA IN THE SYSTEM CAO-IRON OXIDE IN AIR AND AT 1 ATM O2 PRESSURE
PHILLIPS, B
MUAN, A
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1958, 41 (11) : 445 - 454
[10] Pd(II)-Catalyzed C(sp2)-H Hydroxylation with R2(O)P-Coordinating Group
Zhang, Hong-Yu
Yi, Hong-Ming
Wang, Gang-Wei
Yang, Bin
Yang, Shang-Dong
ORGANIC LETTERS, 2013, 15 (24) : 6186 - 6189

← 1 2 3 4 5 →