3,4a-Dichloro-10a-(3-chloro-6-hydroxy-2,2,6-trimethylcyclohexylmethyl)-6,8-dihydroxy-2,2,7-trimethyl-3,4,4a,10a-tetrahydro-2H-benzo[g]chromene-5,10-dione

被引:11
|
作者
Soria-Mercado, IE
Jensen, PR
Fenical, W
Kassel, S
Golen, J
机构
[1] Univ Autonoma Baja California, Fac Ciencias Marinas, Ensenada 22800, Baja California, Mexico
[2] Univ Calif San Diego, Scripps Inst Oceanog, Ctr Marine Biotechnol & Biomed, La Jolla, CA 92093 USA
[3] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA
[4] Villanova Univ, Dept Chem, Villanova, PA 19085 USA
[5] Univ Massachusetts, Dept Chem & Biochem, N Dartmouth, MA 02747 USA
关键词
D O I
10.1107/S1600536804020094
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title microbial antibiotic, C26H33Cl3O6, is an unusual trichlorinated dihydroquinone with cyclized prenyl and geranyl terpene substitution. The crystal structure provides an unambiguous assignment for this compound including its absolute stereochemistry, and shows the favored configuration of the chlorocyclohexane substituent.
引用
收藏
页码:O1627 / O1629
页数:3
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