Relationship between solid-state P-31 NMR parameters and X-ray structural data in some zinc phosphonates

被引：74
|
作者：
Massiot, D
Drumel, S
Janvier, P
BujoliDoeuff, M
Bujoli, B
机构：
[1] URA CNRS 475,ORGAN SYNTH LAB,F-44072 NANTES 03,FRANCE
[2] CTR RECH PHYS HAUTES TEMP,UPR CNRS 4212,F-45071 ORLEANS 02,FRANCE
[3] INST MAT NANTES,UMR CNRS 0110,F-44072 NANTES 03,FRANCE
来源：
CHEMISTRY OF MATERIALS | 1997年 / 9卷 / 01期
关键词：
D O I：
10.1021/cm960417x
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
P-31 solid-state NMR spectroscopy is a powerful tool to get structural information about the environment of the phosphorus atoms in zinc phosphonates. In a series of various known structures taken as reference, the connectivity of the RPO(3) groups (i.e., the number of zinc atoms bonded to each of the three oxygen atoms of the phosphonate units) can be differentiated on the basis of the value of the chemical shift asymmetry and anisotropy.
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页码：6 / &
页数：3
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