Bis{N-[bis(pyrrolidin-1-yl)phosphoryl]-2,2,2-trichloroacetamide}dinitratodioxidouranium(VI)

被引：10
|
作者：
Znovjyak, Kateryna O. [1 ]
Ovchynnikov, Vladimir A. [1 ]
Moroz, Olesia V. [1 ]
Shishkina, Svitlana V. [2 ]
Amirkhanov, Vladimir M. [1 ]
机构：
[1] Kyiv Natl Taras Shevchenko Univ, Dept Chem, UA-01601 Kiev, Ukraine
[2] Natl Acad Sci Ukraine, STC Inst Single Crystals, UA-61001 Kharkov, Ukraine
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷
关键词：
Data-to-parameter ratio = 21.2; Disorder in main residue; Mean σ(C-C) = 0.009 Å; R factor = 0.034; Single-crystal X-ray study; T = 293 K; WR factor = 0.085;
D O I：
10.1107/S1600536810006422
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The crystal structure of the title compound, [U(NO3)(2)O-2-(C10H17Cl3N3O2P)(2)], is composed of centrosymmetric [UO2( L) 2(NO3) 2] molecules {L is N-[bis(pyrrolidin-1-yl) phosphoryl]-2,2,2-trichloroacetamide, C10H17Cl3N3O2P}. The U VI ion, located on an inversion center, is eight-coordinated with axial oxido ligands and six equatorial oxygen atoms of the phosphoryl and nitrate groups in a slightly distorted hexagonal-bipyramidal geometry. One of the pyrrolidine fragments in the ligand is disordered over two conformation (occupancy ratio 0.58:0.42). Intramolecular N-H center dot center dot center dot O hydrogen bonds between the amine and nitrate groups are found.
引用
收藏
页码：M322 / U3749
页数：10
相关论文
共 50 条
  • [31] Non-isothermal kinetic study of the thermal decomposition of N-{bis[benzyl(methyl)amino]phosphoryl}-2,2-dichloroacetamide and N-{bis[dibenzylamino]phosphoryl}-2,2-dichloroacetamide
    Hajimirsadeghi, S. S.
    Teimouri, M. B.
    Rahimi-Nasrabadi, M.
    Dehghanpour, S.
    JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY, 2009, 98 (02) : 463 - 468
  • [32] 2-Chloro-3-(pyrrolidin-1-yl)-1,4-naphthoquinone
    Lynch, DE
    McClenaghan, I
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2000, 56 : E588 - E588
  • [33] SYNTHESIS OF N,N-BIS(ARYL)-N-(2-THIAZOLIN-2-YL)THIOUREAS
    GONZALEZ, MA
    CABALLERO, RB
    MORENO, PC
    REQUEJO, JLJ
    ALBARRAN, JCP
    HETEROCYCLES, 1990, 30 (01) : 463 - 469
  • [34] 2-[2-Hydroxy-4-(pyrrolidin-1-yl)benzoyl]benzoic acid
    Gao, Yun-Long
    Wang, Jian-Wu
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O936 - U3532
  • [35] Bis[1-methoxy-2,2,2-tris(pyrazol-1-yl kappa N-2)ethane]nickel(II)bis(trifluoromethanesulfonate)methanoldisolvate
    Lyubartseva, Ganna
    Parkin, Sean
    Mallik, Uma Prasad
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2013, 69 : M537 - +
  • [36] 1-[(2-Hydroxyphenyl)(pyrrolidin-1-yl)methyl] naphthalen-2-ol N, N-dimethylformamide monosolvate
    Wang, Wen-Xiang
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O884 - U3279
  • [37] ADDITION OF DIMETHYL ACETYLENEDICARBOXYLATE TO 4-(PYRROLIDIN-1-YL)COUMARIN AND TO 1-METHYL-4-(PYRROLIDIN-1-YL)QUINOLIN-2(1H)-ONE
    HAYWOOD, DJ
    REID, ST
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1977, (22): : 2457 - 2458
  • [38] (2S)-4-(methylsulfanyl)-2-(pyrrolidin-1-yl)butanamide
    Song, J
    Li, XJ
    Wu, XP
    Lou, KX
    Feng, RX
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O1290 - O1292
  • [39] μ-η2:η2-Peroxido-bis[nitratodioxidobis(pyrrolidin-2-one)uranium(VI)]
    Takao, Koichiro
    Ikeda, Yasuhisa
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : M539 - U661
  • [40] Bis{[1-(tert-butoxycarbonyl)pyrrolidin-2-yl]methyl} carbonate
    Jing, Lin-Hai
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : O2610 - U2401
12345