Suzuki-Miyaura Coupling of Aryl Carbamates, Carbonates, and Sulfamates

被引：273

作者：

Quasdorf, Kyle W. ^{[1
]}

Riener, Michelle ^{[1
]}

Petrova, Krastina V. ^{[1
]}

Garg, Neil K. ^{[1
]}

机构：

[1] Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2009年 / 131卷 / 49期

关键词：

NICKEL/MAGNESIUM BIMETALLIC COOPERATION; DIRECTED ORTHO-METALATION; GRIGNARD-REAGENTS; POLYSUBSTITUTED AROMATICS; BORONIC ACIDS; ACTIVATION; BOND; CARBOXYLATES; FLURBIPROFEN; FLUORIDES;

D O I：

10.1021/ja906477r

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The first Suzuki-Miyaura cross-couplings of carbamates, carbonates, and sulfamates is described. The method provides a powerful means of using simple derivatives of phenol as precursors to polysubstituted aromatic compounds, as exemplified by a concise synthesis of the anti-inflammatory drug flurbiprofen. © 2009 American Chemical Society.

引用

页码：17748 / 17749

页数：2

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