Structure and properties of the dinuclear complex [Co2(μ-OAc)2(OAc)2(μ-H2O)(phen)2]

The dinuclear complex [Co-2(mu-OAc)(2)(OAc)(2)(mu-H2O)(phen)(2)] has been prepared and its structure was determined. The compound crystallizes in the monoclinic space group P2(1)/c. The Co-Co distance is 3.574 angstrom and is similar to the Fe-Fe distance in the reduced methane monooxygenase hydroxylase. The electronic and IR spectra of the complex confirm octahedral coordination of the cobalt atoms and formation of strong O-H center dot center dot center dot O hydrogen bonds in the solid state. The dependence of the magnetic susceptibility of the complex on temperature indicates an antiferromagnetic interaction, the value of the isotropic exchange parameter J was estimated to be -2.1 cm(-1). The H-1 NMR spectra show that in organic solvents the structure of compound is the same as in the solid state, however, in water solution the complex dissociates giving compounds with different Co:phen ratios. (c) 2006 Elsevier Ltd. All rights reserved.