One-pot tandem enantioselective hydrogenation- hydroformylation synthesis of cyclic α-amino acids

被引：21
|
作者：
Teoh, E
Campi, EM
Jackson, WR
Robinson, AJ
机构：
[1] Monash Univ, Ctr Green Chem, Clayton, Vic 3800, Australia
[2] Monash Univ, Sch Chem, Clayton, Vic 3800, Australia
来源：
NEW JOURNAL OF CHEMISTRY | 2003年 / 27卷 / 02期
关键词：
D O I：
10.1039/b209087m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Five- and six-membered cyclic amino acids can be prepared in good yield with high ee ( > 95%) via tandem rhodium-DuPHOS catalysed asymmetric hydrogenation followed by a rhodium-catalysed hydroformylation cyclisation sequence in a single pot. The synthesis can be achieved using Rh-DuPHOS as the sole catalyst.
引用
收藏
页码：387 / 394
页数：8
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