Synthesis and characterisation of cis-dioxomolybdenum(VI) Schiff base complexes derived from 2-benzoylpyridine

被引：0

作者：

Maurya, RC ^{[1
]}

Mishra, DD ^{[1
]}

Rao, NS ^{[1
]}

Verma, R ^{[1
]}

Rao, NN ^{[1
]}

机构：

[1] CENT SALT & MARINE CHEM RES INST,BHAVNAGAR 364002,GUJARAT,INDIA

来源：

INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY | 1997年 / 36卷 / 07期

关键词：

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

cis-Dioxomolybdenum(VI) complexes of bi-, tri-and tetra-dentate Schiff bases derived from 2-benzoylpyridine and monoamines, such as, p-anisidine, m-phenetidine or p-toluidine, and diamines, viz., o-, mor p-phenylenediamine are reported. Reactions of the bi-, tri-and tetradentate Schiff bases with [MoO2(acac)(2)] in ethanol medium in 1:1, 1:2 and 1:2 molar ratios, respectively, yield diamagnetic molybdenum(VI) monometallic complexes of the composition, cis-[MoO2(L)(OEt)(2)] (where L=bidentate schiff base derived from monoamine) and the ligand bridged bimetallic complexes, cis-[Mo2O4(L-1)(oEt)(4)] (where L'=tridentate schiff base derived from o- or m-phenylenediamine or tetradentate schiff base with p-phenylenediamine). These complexes have been characterized by elemental analyses, molar conductances, IR, UV/Vis, H-1 NMR and CV studies.

引用

页码：599 / 601

页数：3

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