Pursuit of Noncovalent Interactions for Strategic Site-Selective Catalysis

被引：194
|
作者：
Toste, F. Dean [1 ]
Sigman, Matthew S. [2 ]
Miller, Scott J. [3 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
[2] Univ Utah, Dept Chem, 315 S 1400 E, Salt Lake City, UT 84112 USA
[3] Yale Univ, Dept Chem, 225 Prospect St, New Haven, CT 06520 USA
来源：
ACCOUNTS OF CHEMICAL RESEARCH | 2017年 / 50卷 / 03期
基金：
美国国家卫生研究院;
关键词：
ANION PHASE-TRANSFER; ASYMMETRIC CATALYSIS; CHIRAL ANION; NOBEL LECTURE; TEICOPLANIN; ALCOHOLS; STEREOSELECTIVITY; FLUORINATION; DISCOVERY; OXIDATION;
D O I：
10.1021/acs.accounts.6b00613
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Selective reactions on structures of high complexity can move beyond the mind's eye and proof-of principle. Enhanced understanding of noncovalent interactions and their interdependence, revealed through analysis of multiple parameters, should accelerate the discovery of efficient reactions in highly complex molecular environments.
引用
收藏
页码：609 / 615
页数：7
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