Structural Trends in Coordination Polymers Containing Perfluorinated Dicarboxylates and 4,4′-Bipyridine

被引：22

作者：

Hulvey, Zeric ^{[2
]}

Ayala, Elizabeth ^{[2
]}

Cheetham, Anthony K. ^{[1
]}

机构：

[1] Univ Cambridge, Dept Mat Sci & Met, Cambridge CB2 3QZ, England

[2] Univ Calif Santa Barbara, Mat Res Lab, Santa Barbara, CA 93106 USA

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 12期

基金：

欧洲研究理事会; 美国国家科学基金会;

关键词：

Polymers; Cobalt; Zinc; Perfluorinated ligands; Structure elucidation; 4,4 '-bipyridine; METAL-ORGANIC FRAMEWORKS; HYDROGEN STORAGE; CRYSTAL-STRUCTURES; COMPLEXES; SORPTION; SERIES; NET;

D O I：

10.1002/zaac.200900312

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new family of coordination polymers has been synthesized using cobalt or zinc, 4,4'-bipyridine (4,4'-bpy), and the perfluorinated dicarboxylatcs tetrafluoroterephthalate (tftpa), tetrafluorophthalate (tfpha), tetrafluoroisophthalate (tfipa), and tetra fluorosuccinate (tfsuc). These materials form under similar conditions and all display similar octahedral metal coordination environments despite significant differences in their Structures. The compounds M(4,4'-bpy)(tftpa)-(H2O)(2) (M = Co, Zn) (1) and M(4,4'-bpy)(tfpha)(H2O)(2) (M = Co, Zn) (2) are two-dimensional layered structures, whereas Co(4,4'-bpy)-(tfsuc)(H2O)(2) (3) and M(4,4'-bpy)(tfipa)(H2O)(2) (M = Co, Zn) (4) display three-dimensional connectivity built up from two types of interconnected chains.

引用

页码：1753 / 1757

页数：5

共 50 条

[21] STRUCTURE AND ABSORPTION VOLUME FOR HYDROGEN OF ULTRAMICROPOROUS COORDINATION POLYMERS OF COPPER(II) WITH 4,4′-BIPYRIDINE
Mikhalyova, E. A.
Kolotilov, S. V.
Gavrilenko, K. S.
Nagornyi, P. G.
Golhen, S.
Ouahab, L.
Pavlishchuk, V. V.
THEORETICAL AND EXPERIMENTAL CHEMISTRY, 2008, 44 (04) : 245 - 251
[22] Syntheses and structures of Zn coordination polymers with 4,4′-bipyridine and 4,4′-azopyridine.: Effect of counter anions on the network system
Kondo, M
Shimamura, M
Noro, S
Yoshitomi, T
Minakoshi, S
Kitagawa, S
CHEMISTRY LETTERS, 1999, (04) : 285 - 286
[23] Crystal structure of ∞2[Cu2I2(μ-4,4′-bipyridine)] and investigations on the thermal decomposition of CuX-4,4′-bipyridine coordination polymers
Näther, C
Jess, I
MONATSHEFTE FUR CHEMIE, 2001, 132 (08): : 897 - 910
[24] Alkyl group dependence on structure and magnetic properties in layered cobalt coordination polymers containing substituted glutarate ligands and 4,4′-bipyridine
Nettleman, Joseph H.
Supkowski, Ronald M.
LaDuca, Robert L.
JOURNAL OF SOLID STATE CHEMISTRY, 2010, 183 (02) : 291 - 303
[25] BINUCLEAR COMPOUNDS OF TIN CONTAINING 4,4'-BIPYRIDINE
BASSETH, C
BAJUE, SA
BRAMWELL, FB
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1991, 201 : 248 - INOR
[26] SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF A Zn(II) COORDINATION POLYMER BASED ON 4,4 '-BIPYRIDINE AND ACETATO
Wang, Li-Hua
SCIENTIFIC STUDY AND RESEARCH-CHEMISTRY AND CHEMICAL ENGINEERING BIOTECHNOLOGY FOOD INDUSTRY, 2015, 16 (01): : 81 - 85
[27] Crystal engineering of coordination polymers using 4,4′-bipyridine as a bond between transition metal atoms
Biradha, Kumar
Sarkar, Madhushree
Rajput, Lalit
CHEMICAL COMMUNICATIONS, 2006, (40) : 4169 - 4179
[28] Copper dimethylmalonate coordination polymers with 4,4′-bipyridine coligands: Kinetic and thermodynamic products with different dimensionalities
Stone, Brandon S.
Sample, Alexander D.
LaDuca, Robert L.
INORGANICA CHIMICA ACTA, 2015, 438 : 52 - 57
[29] Synthesis and Structural Characterization of a Ni(II) Coordination Polymer Based on 4,4′-Bipyridine and Acetato
Wang, Lihua
Lin, DanDan
Liang, Qian
2018 4TH INTERNATIONAL CONFERENCE ON ENVIRONMENTAL SCIENCE AND MATERIAL APPLICATION, 2019, 252
[30] Synthon Robustness and Structural Modularity of Copper(II) Two-Dimensional Coordination Polymers with Isomeric Amino Acids and 4,4′-Bipyridine
Smokrovic, Kristina
Muratovic, Senada
Karadeniz, Bahar
Uzarevic, Krunoslav
Zilic, Dijana
Dilovic, Ivica
CRYSTAL GROWTH & DESIGN, 2020, 20 (04) : 2415 - 2423

← 1 2 3 4 5 →