Thermodynamics of solvation of proton and chloride ion in alcohols

被引：0
|
作者：
Bulavin, VI [1 ]
机构：
[1] Kharkov State Polytech Univ, Kharkov, Ukraine
来源：
RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 1999年 / 69卷 / 12期
关键词：
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A method is proposed for estimating the solvation entropy, enthalpy, and Gibbs free energy of individual H+ and Cl- ions in a series of alcohols, based on the previously derived correlation equations. Proton and chloride ion solvation in a series of alcohols from methanol to nonanol at 278.15-328.15 K (at a 10 K step) is thermodynamically analyzed. It is shown that the solvation of hydrogen chloride is essentially determined by proton solvation.
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页码：1875 / 1878
页数：4
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