Conductance and viscosity studies of some univalent electrolytes in water, dimethyl sulfoxide and water plus dimethyl sulfoxide mixtures at different temperatures

被引:0
|
作者
Syal, VK [1 ]
Chauhan, S [1 ]
Gupta, PK [1 ]
机构
[1] Himachal Pradesh Univ, Dept Chem, Shimla 171005, Himachal Prades, India
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中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conductance and viscosity of sonic univalent electrolytes have been measured. in water, dimethyl sulfoxide (DMSO) and water + DMSO mixtures at different temperatures. The limiting molar conductance (Lambda(o)), limiting ionic conductances (lambda(1o)), Walden products (lambda(lo)eta(o)), solvated radii (r(i)), viscosity A and B coefficients and ionic B+/- values have been evaluated. These studies throw light on the effect of nature of electrolyte, solvent composition and temperature on the solvation behavior of ions in DMSO and DMSO + water mixtures.
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页码:860 / 865
页数:6
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