Experimental and theoretical investigation of the spectral and luminescent properties of some acridine compounds

被引：18

作者：

Samsonova, L. G. ^{[1
]}

Selivanov, N. I. ^{[1
]}

Kopylova, T. N. ^{[1
]}

Artyukhov, V. Ya. ^{[1
]}

Maier, G. V. ^{[1
]}

Plotnikov, V. G. ^{[2
]}

Sazhnikov, V. A. ^{[2
]}

Khlebunov, A. A. ^{[2
]}

Alfimov, M. V. ^{[2
]}

机构：

[1] Tomsk State Univ, Pr Lenina 36, Tomsk 634050, Russia

[2] Russian Acad Sci, Photochem Ctr, Moscow 119421, Russia

来源：

HIGH ENERGY CHEMISTRY | 2009年 / 43卷 / 02期

关键词：

ELECTRONIC ABSORPTION; CHARGE-TRANSFER; SENSORS; FLUORESCENCE; CONVERSION; BASES;

D O I：

10.1134/S0018143909020076

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Complex (experimental and quantum-chemical) investigation of the spectral and luminescent properties of acridine, 9-aminoacridine, 2,7-dimethyl-9-ditolylaminoacridine, and their protonated forms was performed. The electronic absorption and fluorescence spectra of the acridine dyes were studied at room temperature in ethanolic solutions at different pH values and in other solvents of different chemical nature and polarity. The energies of the excited states, the deactivation rate constants for the excited states, and the dipole moments are presented, which were obtained by calculations using the method of intermediate neglect of the differential overlap with special spectroscopic parameterization.

引用

页码：105 / 115

页数：11

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