Cathodic coupling of ketones with trimethylsilyl substituted allyl alcohols

被引：2
|
作者：
Kashimura, S
Ishifune, M
Murai, Y
Shono, T
机构：
[1] KINKI UNIV,DEPT MET,HIGASHIOSAKA,OSAKA 577,JAPAN
[2] KINKI UNIV,DEPT APPL CHEM,HIGASHIOSAKA,OSAKA 577,JAPAN
[3] KINKI UNIV,SCI & TECHNOL RES INST,HIGASHIOSAKA,OSAKA 577,JAPAN
来源：
TETRAHEDRON LETTERS | 1996年 / 37卷 / 37期
关键词：
D O I：
10.1016/S0040-4039(96)01455-4
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Cathodic coupling of ketones with 3-(trimethylsiiyl)allyl alcohols has been found to give trimethylsilyl substituted 1,3-diols with high diastereoselectivity, whereas that with 2-(trimethylsilyl)allyl alcohols afforded homoallylic alcohols through the Peterson elimination of intermediately formed trimethylsilyl substituted 1,4-diols. Copyright (C) 1996 Elsevier Science Ltd
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页码：6737 / 6740
页数：4
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