Regioselectivity in Hydroformylation of Aryl Olefins Using Novel Rhodium Polyether Phosphinite Catalysts

被引：17
|
作者：
Panda, Anil G. [1 ]
Bhor, Malhari D. [1 ]
Ekbote, Sunil S. [1 ]
Bhanage, Bhalchandra M. [1 ]
机构：
[1] Inst Chem Technol Autonomous, Dept Chem, Bombay 400019, Maharashtra, India
来源：
CATALYSIS LETTERS | 2009年 / 131卷 / 3-4期
关键词：
Hydroformylation; Styrene; Polymeric Rh catalyst; Polyethylene glycol; ASYMMETRIC HYDROFORMYLATION; COMPLEXES; STYRENE; SILICA;
D O I：
10.1007/s10562-009-0001-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Polyethylene glycol based diphosphinite ligands and their Wilkinson type Rh-polymeric carbonyl complexes were prepared for homogeneous hydroformylation of styrenes. The effect of reaction variables such as temperature, pressure, P/Rh ratio, Substrate/Rh ratio, phosphine and phosphinite ligands on the activity and selectivity performance were discussed in detail. The catalyst showed a high rate of reaction, TON and tunable regioselectivity depending upon reaction conditions as compared to conventional Rh-phosphine based catalysts.
引用
收藏
页码：649 / 655
页数：7
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