Syntheses and structures of (pentamethylcyclopentadienyl)iridium amidinate complexes

被引：19

作者：

Simpson, RD

Marshall, WJ

机构：

[1] Mat. Sci. and Eng. Laboratories, Ctrl. R. and D. Department, E. I. DuPont de Nemours and Co. Inc., Wilmington

来源：

ORGANOMETALLICS | 1997年 / 16卷 / 16期

关键词：

D O I：

10.1021/om961095+

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of [Cp*IrCl2] with lithium amidinates provides an entry to a series of Cp*Ir(RNR'CNR)X (1, X = Cl 2, X = Br) complexes. Alkyl or hydride derivatives are formed by addition, of a variety of Grignard reagents or sodium isopropoxide to 1 or 2. Cationic complexes may be obtained by the interaction of 2 with AgSbF6 in the presence of an appropriate ligand. In all of these compounds, the amidinate ligand adopts a symmetrical, bidentate coordination geometry.

引用

页码：3719 / 3722

页数：4

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