On the molar volumes and viscosities of electrolytes

被引：5

作者：

Marcus, Yizhak ^{[1
]}

机构：

[1] Hebrew Univ Jerusalem, Dept Inorgan & Analyt Chem, IL-91904 Jerusalem, Israel

来源：

JOURNAL OF SOLUTION CHEMISTRY | 2006年 / 35卷 / 09期

关键词：

apparent molar volume; aqueous electrolytes; non-aqueous solutions; viscosity B-coefficient;

D O I：

10.1007/s10953-006-9058-5

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The b (V) coefficient of the term linear with the concentration of the apparent molar volume V-phi of electrolytes in water and several non-aqueous solvents is examined. Its relationship with the B (eta) coefficient of the corresponding term in the relative viscosity of these electrolyte solutions is explored. Positive correlations are found in some cases as expected, but in others, where crowding of the solvation shells occurs on increasing concentration, such correlations fail.

引用

页码：1271 / 1286

页数：16

共 50 条

[21] EXCESS MOLAR VOLUMES OF TERNARY MIXTURES OF NON-ELECTROLYTES
NIGAM, RK
AGGARWAL, S
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1988, 27 (08): : 719 - 720
[22] DILATOMETRIC MEASUREMENTS OF APPARENT MOLAR VOLUMES OF DILUTE AQUEOUS ELECTROLYTES
HEPLER, LG
STOKES, JM
STOKES, RH
TRANSACTIONS OF THE FARADAY SOCIETY, 1965, 61 (505P): : 20 - &
[23] Apparent molar volumes and viscosities of DL-α-alanine in water-ethanol mixtures
Romero, CM
Rojas, JL
PHYSICS AND CHEMISTRY OF LIQUIDS, 2000, 38 (02) : 237 - 243
[24] Partial molar volumes and viscosities of some α-amino acids in micellar solutions of sodium caprylate
Wang, JJ
Yan, ZN
Zhao, Y
Cui, FL
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (05): : 1354 - 1358
[25] VISCOSITIES AND EXCESS MOLAR VOLUMES FOR ACETONITRILE PLUS METHANOL AT 298.15, 308.15, AND 318.15 K
SAHA, N
DAS, B
HAZRA, DK
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1995, 40 (06): : 1264 - 1266
[26] EXCESS MOLAR VOLUMES AND VISCOSITIES OF 10 BINARY AND 4 TERNARY LIQUID-MIXTURES
AMINABHAVI, TM
JOSHI, SS
INDIAN JOURNAL OF TECHNOLOGY, 1992, 30 (04): : 197 - 208
[27] VISCOSITIES AND MOLAR VOLUMES OF SOME SPECIALLY SELECTED LIQUID-MIXTURES AT 298.15 K
GALLANT, P
HIRSCH, W
FRIED, V
PHYSICS AND CHEMISTRY OF LIQUIDS, 1988, 18 (01) : 21 - 30
[28] Excess molar volumes and viscosities of binary mixtures of some polyethers with propylamine at 298.15 K
Pal, A
Bhardwaj, RK
CANADIAN JOURNAL OF CHEMISTRY, 2002, 80 (05) : 467 - 475
[29] Densities, excess molar volumes, viscosities of binary mixtures of ethanediol with water at various temperatures
Kapadi, UR
Hundiwale, DG
Patil, NB
Patil, PR
Lande, MK
JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2000, 77 (07) : 319 - 321
[30] On the concentration dependence of apparent molar volumes of some strong electrolytes.
Kruis, A
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-ABTEILUNG B-CHEMIE DER ELEMENTARPROZESSE AUFBAU DER MATERIE, 1936, 34 (1/2): : 1 - 12

← 1 2 3 4 5 →