Toxicity and biodegradation of chlorophenols in anaerobic propionate enrichment culture

被引:13
|
作者
Jin, PK [1 ]
Bhattacharya, SK [1 ]
机构
[1] TULANE UNIV,DEPT CIVIL & ENVIRONM ENGN,NEW ORLEANS,LA 70118
关键词
anaerobic treatment; biodegradation; chlorophenols; dechlorination; methanogens; propionate; toxic compounds;
D O I
10.2175/106143097X125623
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The fate of four trichlorophenols (TCP), six dichlorophenols (DCP), and three monochlorophenols (CP), were studied in anaerobic propionate enrichment systems. TCPs were more toxic than DCPs and CPs; 2,4,5-TCP was most toxic to the propionate users among the 13 chlorophenols studied in this research. Most chlorophenols were dechlorinated reductively to less chlorinated compounds and/or phenol. Dechlorination at the ortho position was observed most frequently. The overall removal of the selected chlorophenols by anaerobic propionate enrichment systems were in the following order: 2,3,5-TCP > 2,3,6-TCP > 3,5-DCP > 2,4-DCP > 2-CP > 3,4-DCP; 2,3-DCP; 2,5-DCP > 3-CP, 2,4,5-TCP > 2,6-DCP > 2,4,6-TCP > 4-CP.
引用
收藏
页码:938 / 947
页数:10
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