A new synthesis of limonene copolymer: experimental and theoretical analysis

被引：7

作者：

Cankaya, Nevin ^{[1
]}

Tanis, Emine ^{[2
]}

Gulbas, H. Elmali ^{[3
]}

Bulut, Niyazi ^{[4
]}

机构：

[1] Univ Usak, Dept Chem, Usak, Turkey

[2] Ahi Evran Univ, Kaman Vocat Sch, Kirsehir, Turkey

[3] Usak Univ, Chem Technol, Usak, Turkey

[4] Firat Univ, Dept Phys, Elazig, Turkey

来源：

POLYMER BULLETIN | 2019年 / 76卷 / 07期

关键词：

2-(4-Methoxyphenylamino)-2-oxoethyl methacrylate (MPAEMA); Limonene; LIM-co-MPAEMA; Density functional theory (DFT); DENSITY-FUNCTIONAL THEORY; GAS-PHASE; CHEMICAL-REACTIVITY; AB-INITIO; TOXICITY; HARDNESS;

D O I：

10.1007/s00289-018-2543-3

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

A copolymer of limonene with 2-(4-methoxyphenylamino)-2-oxoethyl methacrylate (LIM-co-MPAEMA) which is thought to be a non-toxic and used generally as a dietary supplement was synthesized and characterized for the first time both experimentally and theoretically. The structure of synthesized limonene copolymer was chemically characterized by Fourier transform infrared and nuclear magnetic resonant (H-1 NMR) spectroscopic techniques and compared with the theoretical calculated results. Charge transfer that is important in the formation of chemically bonded adducts causing cancer is quantitatively calculated. It was found that this polymer can be used as a biomaterial.

引用

页码：3297 / 3327

页数：31

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