Experimental analysis of SO2 effects on Molten Carbonate Fuel Cells

被引：12

作者：

Di Giulio, N. ^{[1
,2
]}

Bosio, B. ^{[1
]}

Han, J. ^{[2
,3
]}

McPhail, S. J. ^{[4
]}

机构：

[1] Univ Genoa, DICCA, PERT, I-16145 Genoa, Italy

[2] Korea Inst Sci & Technol, Fuel Cell Res Ctr, Seoul 136791, South Korea

[3] Korea Univ, Green Sch, Seoul 136713, South Korea

[4] ENEA, Casaccia Res Ctr, I-00123 Rome, Italy

来源：

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY | 2014年 / 39卷 / 23期

基金：

新加坡国家研究基金会;

关键词：

Molten Carbonate Fuel Cells; Fuel contaminants; Sulphur dioxide; Poisoning mechanism; Performance decay; SULFUR; H2S;

D O I：

10.1016/j.ijhydene.2014.04.120

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The aim of this work is to investigate how SO2 can affect MCFC performance and to discover the possible mechanisms involved in cathode sulphur poisoning, specifically considering the possible use of MCFCs in CCS (Carbon Capture and Storage) application. The different contributions of cathodic, anodic and electrolyte reactions have been considered to get a complete picture of the evolution of performance degradation. Experimental tests have been performed at the Fuel Cell Centre laboratories of Korea Institute of Science and Technology (KIST) thanks to 100 cm(2) single cell facilities and comparing results using both an optimized gas for laboratory conditions and a gas composition that simulates MCFCs when running in a Natural Gas Combined Cycle (NGCC) power plant. Polarisation curves, endurance tests, impedance measurements and gas analyses have been carried out to support the investigation. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.

引用

页码：12300 / 12308

页数：9

共 50 条

[21] CELL ASSEMBLIES FOR A MOLTEN CARBONATE FUEL BATTERY .2. ELECTROLYTE PASTE DISKS FOR MOLTEN CARBONATE FUEL-CELLS
HUYNINK, HE
ENERGY CONVERSION, 1972, 12 (04): : 139 - &
[22] Effects of marine atmosphere on the cell performance in molten carbonate fuel cells
Song, Shin Ae
Kim, Hyun Koo
Ham, Hyung Chul
Han, Jonghee
Nam, Suk Woo
Yoon, Sung Pil
JOURNAL OF POWER SOURCES, 2013, 232 : 17 - 22
[23] EFFECTS OF SEVERAL TRACE CONTAMINANTS ON MOLTEN CARBONATE FUEL-CELLS
PARK, SM
OBRIEN, TJ
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1981, 128 (03) : C115 - C115
[24] Carbon capture with molten carbonate fuel cells: Experimental tests and fuel cell performance assessment
Discepoli, Gabriele
Cinti, Giovanni
Desideri, Umberto
Penchini, Daniele
Proietti, Stefania
INTERNATIONAL JOURNAL OF GREENHOUSE GAS CONTROL, 2012, 9 : 372 - 384
[25] Experimental Investigation on a Novel Electrolyte Configuration for Cylindrical Molten Carbonate Fuel Cells
Rossi, Federico
Nicolini, Andrea
JOURNAL OF FUEL CELL SCIENCE AND TECHNOLOGY, 2011, 8 (05):
[26] Development and Experimental Research of kW-scale Molten Carbonate Fuel Cells
沈承
HighTechnologyLetters, 2002, (01) : 86 - 91
[27] Development and experimental research of kW-scale molten carbonate fuel cells
Shen, Cheng
Zhu, Xinjian
Cao, Guangyi
High Technology Letters, 2002, 8 (01) : 86 - 91
[28] Phase and microstructure stabilities of LiAlO2 in molten Li/Na carbonate for molten carbonate fuel cells
Kim, SD
Hyun, SH
Shin, MY
Lim, TH
Hong, SA
Lim, HC
JOURNAL OF POWER SOURCES, 2005, 143 (1-2) : 24 - 29
[29] VNIIEF research on Molten Carbonate Fuel Cells
Potyomkin, GA
Kozhuhar, NG
Anissin, AV
Batalov, NN
Malevanny, SI
Malishev, A
Postnikov, AY
CARBONATE FUEL CELL TECHNOLOGY, 1999, 99 (20): : 80 - 89
[30] MIXED POTENTIAL ANALYSIS OF SULFATION OF MOLTEN CARBONATE FUEL-CELLS
TOWNLEY, D
WINNICK, J
HUANG, HS
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1980, 127 (05) : 1104 - 1106

← 1 2 3 4 5 →