An efficient triazole-pyridine-bistetrazolate platform for highly luminescent lanthanide complexes

被引：30
|
作者：
Di Pietro, S. [1 ,2 ]
Imbert, D. [1 ,2 ]
Mazzanti, M. [1 ,2 ]
机构：
[1] CEA, INAC SCIB, F-38000 Grenoble, France
[2] Univ Grenoble Alpes, INAC SCIB, F-38000 Grenoble, France
来源：
CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 71期
关键词：
PHOTOPHYSICAL PROPERTIES; LIGANDS; COORDINATION; SENSITIZER; IONS;
D O I：
10.1039/c4cc04060k
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Two new triazole-pyridine-bistetrazolate ligands were synthesized via a versatile procedure that allows for further derivatization; their corresponding homoleptic tris-ligand nona-coordinated lanthanide complexes are highly luminescent in the solid state and in a PVA polymeric matrix with measured values for the luminescence quantum yield of 70(7) and 98(9)% for Eu-III and Tb-III, respectively.
引用
收藏
页码：10323 / 10326
页数：4
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