Mononuclear metavanadate catalyses gas phase oxidation of methanol to formaldehyde employing dioxygen as the terminal oxidant

被引:43
|
作者
Waters, Tom
Khairallah, George N.
Wimala, Samantha A. S. Y.
Ang, Yien C.
O'Hair, Richard A. J. [1 ]
Wedd, Anthony G.
机构
[1] Univ Melbourne, Sch Chem, Parkville, Vic 3010, Australia
[2] Univ Melbourne, Inst Mol Sci & Biotechnol Bio21, Parkville, Vic 3010, Australia
关键词
D O I
10.1039/b612384h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Multistage mass spectrometry experiments reveal a sequence of gas phase reactions for the oxidation of methanol to formaldehyde with a mononuclear oxo vanadate anion as the catalyst and dioxygen as the terminal oxidant.
引用
收藏
页码:4503 / 4505
页数:3
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